Dipolar excitations at the LIII x-ray absorption edges of the heavy rare-earth metals.
نویسندگان
چکیده
We report measured dipolar asymmetry ratios at the LIII edges of the heavy rare-earth metals. The results are compared with a first-principles calculation and excellent agreement is found. A simple model of the scattering is developed, enabling us to reinterpret the resonant x-ray scattering in these materials and to identify the peaks in the asymmetry ratios with features in the spin and orbital moment densities.
منابع مشابه
Multielectron Excitations Above the Xenon L Edges
The X-ray absorption cross section ahove the L edges in Xenon gas has been measured using synchrotron radiation. Multielectron excitation effects are investigated over a few hundred eV region from the Xe-LI, LII. and LIII edges and thc contrihutions from the effects of shakenp and shakeoff to the photoahsorption spectrum are elucidated. Several features for the multielectron excitations were de...
متن کاملContinuous Cauchy wavelet transform analyses of EXAFS spectra: A qualitative approach
To better understand the extended x-ray absorption fine structure (EXAFS) spectroscopic information obtained for complex materials such as those encountered in Earth sciences, we propose to use the Continuous Cauchy Wavelet Transform (CCWT). Thanks to this method, the EXAFS spectra can be visualized in three-dimension: the wavevector (k), the interatomic distance uncorrected for phase-shifts (R...
متن کاملارزیابی مقادیر فلزات سنگین در ذرات گرد و غبار باریده بر شهرهای سنندج، خرم آباد و اندیمشک در غرب ایران1392-1391
Background & Objectives: Dust storms happening frequently in arid and semiarid regions of the world carry huge amount of particulate matters hence, these are recognized as one of the most important environmental issues at regional and international scales. This study aimed to evaluate heavy metals laden dustfall particles in Sanandaj, Khoramabad, and Andimeshk cities, West Iran. Materials & Met...
متن کاملMechanical activation of phosphate concentrates to enhance dissolution efficiency of rare earth elements from a kinetic viewpoint
The Esfordi phosphate concentrate mainly contains fluorapatite, monazite, and xenotime as rare earth element (REE) minerals, accounting for 1.5% of rare earth metals. The monazite and xenotime minerals are refractory and their decomposition is only possible at high temperatures. Thus mechanical activation was used in the present work for this purpose. After 90 minutes of mechanical activation, ...
متن کاملInelastic X-ray Scattering by Electronic Excitations in Solids at High Pressure
Investigating electronic structure and excitations under extreme conditions gives access to a rich variety of phenomena. High pressure typically induces behavior such as magnetic collapse and the insulator-metal transition in 3d transition metals compounds, valence fluctuations or Kondo-like characteristics in f -electron systems, and coordination and bonding changes in molecular solids and gla...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
- Physical review letters
دوره 102 12 شماره
صفحات -
تاریخ انتشار 2007